SILIKE SILIMER PFAS-Free PPA Product Forms for Polyolefins and Selected Engineering Thermoplastics (PET, PBT, PA, PC)
To support global masterbatch producers, compounders, and downstream converters, SILIKE offers sustainable PFAS-free processing additives in two main product forms, providing flexible formulation and processing options.
• 100% Pure PFAS -free polymer processing additives(PPAs)
(For Resin Production / Compounding Stage)
For high-precision compounding applications requiring full formulation control, SILIMER 9400, SILIMER 9300, SILIMER 9200, and SILIMER 9100 series are supplied as 100% active, fluorine-free polymer processing additives designed to enhance the processing performance of various polyolefins.
These grades are primarily used in the formulation of functional masterbatches. They can be incorporated into polymer systems via compounding and then further processed into customized masterbatches for downstream film, cable, pipe, fiber, and other extrusion applications.
Based on organically modified polysiloxane chemistry, these additives combine the lubricating characteristics of polysiloxanes with functional polar groups, enabling effective dispersion and controlled activity within the polymer melt during processing. This provides processing performance comparable to fluorinated PPA systems across a wide range of applications.
At low addition levels, they help mitigate melt fracture, improve surface quality, and reduce surface defects and gel formation. They also support reduced die build-up, improved processing stability, lower operating pressure, and enhanced production efficiency under demanding extrusion conditions.
Overall, they represent a fluorine-free alternative to conventional fluoropolymer-based PPAs.
• Carrier-Based fluorine-free Masterbatch Systems
(For Direct Industrial Use)
The SILIMER PFAS-free PPA masterbatch series is based on modified polysiloxane functional systems carried in PE, PP, and other resin matrices. Grades such as SILIMER 9406, SILIMER 9301, SILIMER 9201, and SILIMER 5090 are designed to provide effective processing aid functionality during extrusion.
During processing, the active components provide interfacial lubrication at the die, improving melt flow stability and surface quality while reducing die drool, melt fracture, and processing instability.
These Non-PFAS Process Aids Masterbatch products are widely used in film, pipe, sheet, fiber, artificial grass, and wire & cable applications.
SILIMER PFAS-Free PPA Incorporation Procedure
SILIMER PFAS-free PPAs are designed for flexible integration into polyolefin and engineering polymer systems. They can be introduced at different stages depending on production configuration and processing requirements.
• Resin Production / Compounding Stage
– Direct addition during resin manufacturing or compounding for uniform distribution within the polymer matrix
– Alternatively supplied as a masterbatch or concentrate for controlled dosing in downstream processing
• Downstream Processing Stage
– Addition via masterbatch let-down during extrusion or conversion processes, adjusted according to processing conditions and performance targets
SILIMER products are compatible with conventional extrusion and compounding systems and are designed to support stable processing without requiring equipment modification.
PFAS-Free Processing Aid Solutions for Extrusion Applications
The value of a PFAS-free processing aid is ultimately validated under real-world, high-speed extrusion conditions. At recent industry exhibitions, SILIKE demonstrated successful commercial applications of its SILIMER PFAS-free processing aid series across a broad range of polyolefin and recycled polyolefin resin processing systems, including blown film, cast film, and multilayer film extrusion, as well as fiber and monofilament production, cable and pipe extrusion, masterbatch manufacturing, and compounding applications. These application cases demonstrate that fluorine-free processing solutions can effectively replace conventional fluoropolymer-based PPAs while maintaining stable processing performance, consistent surface quality, and high production efficiency under demanding industrial conditions.
Proven Performance Across Key Polyolefin Extrusion Applications
| Application Sector | Common Processing Issues & Quality Defects | SILIKE SILIMER Series Fluorine-free/ PFAS-free polymer processing aids (PPAs) Key Performance Improvements |
| Blown Film Systems (HDPE, LDPE, LLDPE / mLLDPE) | shark skin, localized gel formation, die build-up. | Helps mitigate melt fracture (sharkskin) at appropriate usage levels, supporting more stable extrusion performance across a broad range of polyolefins. It assists in reducing die build-up and the tendency for gel formation, contributing to cleaner processing conditions. In film applications, it may help stabilize bubble inflation and broaden the workable processing window, improving overall operational consistency. |
| Cast Film Systems | High shear stress, rapid die lip contamination, high downtime for cleaning. | Supports more stable melt flow and die lip stability, enabling improved film formation and surface quality. It can help lower gel and crystal point formation while maintaining cleaner dies during extended production runs. At appropriate addition levels, it is generally designed to have minimal impact on optical properties such as clarity and gloss, while supporting more efficient and continuous operation. |
| Multilayer Co-Extrusion | Viscosity mismatches between layers, interfacial flow disturbances, haziness. | Enhances layer-to-layer melt flow balance and die stability in multilayer co-extrusion, helping reduce die build-up and enabling more uniform layer distribution. This contributes to stable processing, consistent surface quality, and reduced downtime, with minimal impact on downstream converting operations such as printing, lamination, and heat sealing at appropriate usage levels. |
| Pipe Extrusion (HDPE, MDPE, LLDPE, LDPE, PP, PP-R& PE-RT and PVC) | High backpressure, processing defects caused by carbon black/pigment loading. | Helps optimize melt flow and interfacial lubrication during extrusion, supporting smoother material transport and more stable processing. This contributes to lower extrusion back pressure and reduced die build-up, enabling more consistent operation and improved overall throughput. |
| Wire & Cable Extrusion | Surface defects, die drool, frequent line stops. | Improves melt flow stability and helps minimize die build-up and equipment fouling, supporting more uniform insulation surfaces and improved processing stability. |
| Fiber & Monofilament (such as artificial grass and synthetic turf) | Screen pack fouling, strand breakage, equipment buildup. | Reduces die and equipment build-up, helping maintain more stable extrusion conditions and smoother processing. It improves melt flow behavior, enabling more uniform fiber and monofilament formation and reducing the risk of strand breakage. This helps reduce cleaning frequency and unplanned downtime, contributing to improved overall production efficiency. |
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Conclusion: Driving Global Sustainability with Industrial Precision
As the global polymer market continues to move away from hazardous chemical additives, waiting to adapt is no longer an option for forward-thinking brands. Traditional loose fluoropolymer powders and legacy PPAs have reached the end of their lifecycle in premium manufacturing.
By partnering with Chengdu SILIKE Technology Co., Ltd. and integrating the industrially validated SILIMER series, a fluorine-free polymer processing aid solution, global polymer processors can achieve a dual advantage: supporting compliance with stringent international environmental regulations such as REACH, RoHS, and the EU PPWR framework, while simultaneously optimizing their manufacturing throughput and surface quality.
To explore detailed technical documentation of Non-PFAS polymer processing aids for extrusion applications, including application case studies in films, pipes, wire & cable, and fiber & monofilament (such as artificial grass and synthetic turf), or to schedule a custom formulation consultation with our materials engineering team, please visit the official SILIKE corporate portal at https://www.siliketech.com/.
SILIKE’s global application specialists are ready to support your technical team in achieving a smooth and efficient transition toward sustainable, fluorine-free extrusion processes.